Even with a boatload of mold release, you likely would not get your foam bird out.
Check-out Smooth-On, Inc. Search for Rebound 25 and watch the mold making videos...
Now:
Why not just coat the decoy you intend to make copies of with a sealer(several coats of urethane) and then Rebound 25 (3-6 coats); the initial coat should be very thin, building the mold's thickness up with subsequent coats. Next, cover with a polystyrene resin and fiberglass coating;mark the longitudinal midline of the decoy and form a vertical fin-like ridge out of non-sulfur containing clay down the midline of the bird; now, cover the vertical face of this fin with foil. When complete, add another two fiberglass polystyrene resin layers over the non-fin side. When this is dry, remove the clay, but leave the thin layer of foil in place to enable you to seperate the two sides of the containment shell. Lay another 2 layers of figerglass on the other mold half to form a second fin over the remaining half of the shell. You now have a Rebound/decoy complex to foam and a hard containement shell over the silicone mold. Now, split the fiberglass shell vertically into its two halfves. Do no cut into the silicone mold. Clamp the shell back together and drill several (4-5) holes through the vertical fin, after removing the clay layer and foil. Now, all you have to do is bolt the fiberglass shell pieces together around the mold after removing the decoy body master. Bolt the 3" fiberglass and silicone lip around the mold body to a 1/4" thick plexiglass sheet by drilling a series of holes for even bolt spacing and placement. Now you have a rigid container surrounding your silicone mastermold. All you need do now is fill the void where the decoy was with water, pour it off into a measuring cup to determine the mold's volume and let the mold dry.
With the mold volume now known, you can mix two part foam (8lb)and pour it through several 3/4" pour holes in the plexiglass in an exact quantity to minimize waste via overexpansion. Some guys clamp the mold and plexiglass unit to a piece of shelving to force the foam to expand fully within the mold to get a slightly denser decoy.
I prefer to add a styrene plastic(Smooth Cast 300) layer after I spray the mold with release agent to get a hard shell that will surround the foam decoy body.
You can knock out about forty decoys before the Rebound master mold begins to deteriorate(it will start to turn white in the sections that are starting to stress from the heat generated from the expanding foam reaction). Fifty-seven is my maximum per mold...