If you plan to spray, know that sometimes clovers are hard to terminate with Glyphosate (Roundup) alone. 2-4,D will terminate the clover better than Gly but it has a residual effect in the soil and you will need to wait a while before you can plant another broadleaf forage. If you apply 1 pint/acre you should wait a week or two before planting. If you apply 2-4,D at 1 quart/acre you should wait 4 weeks before planting.
Another option would be to spray with "Liberty" (24.5% Glufosinate), although there are generic versions that contain the same Active Ingredient (24.5% Glufosinate) which are much cheaper (Cheetah, Surmise and Interline come to mind). I just purchased 2.5 gallons of Interline at Keystone Pest Solutions and it did a great job of terminating my alfalfa/clovers really fast. There is no residual waiting period with Glufosinate.
Interline Herbicide 2.5 Gallons (Same AI as Surmise, Cheetah, Liberty)
If you are planning to drill the brassica seed you could do that any time
after the herbicide has dried. If you plan to till the clovers under, you would be best to wait a week or so after spraying to allow the herbicide to do its thing prior to tilling.
Tillage will, no doubt, bring up weed seeds in the soil bank and they will germinate soon after tilling and rain. If you can wait a week or so after those seeds come up you could spray again just prior to planting (with just Glyphosate) and then plant the brassicas without too much more soil disturbance for a fairly weed free plot. The nice thing about brassicas is that they will canopy fast and block out a lot of weed growth.
The biggest thing we all had to learn about planting brassicas is that it is very easy to plant
WAY TOO MUCH SEED.
You would be far better off to plant too little seed as opposed to too much. Too much seed results in many, many stunted plants that will grow only very small leaves and bulbs.
The Dbltree method is a very good strategy for feeding deer. Planting brassicas following the clovers (legumes) will allow you to take advantage of some free atmospheric Nitrogen that the clovers should have fixed in their roots.
Best of luck.